1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐 CAS 64536-78-3

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate 64536-78-3 (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)-IR(I) PF6;(1,5-CYCLOOCTADIENE)PYRIDINE(TRICYCLOHEXYLPHOSPHINE)IRIDIUM HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-CYCLOOCTADIENE(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;CRABTREE PRECURSOR COMPLEX;CRABTREE'S CATALYST;IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX;[IR(COD)(PCY3)(PY)]PF6 SC10616

纯度 97%+现货药物标准品
CAS 号64536-78-3
分子式C18H33P Ir F6P C8H12 C5H11N
分子量N/A g/mol
分类药物标准品 / 原料药标准品
库存状态现货

化学结构式 Structure

1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐 (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate 64536-78-3 (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)-IR(I) PF6;(1,5-CYCLOOCTADIENE)PYRIDINE(TRICYCLOHEXYLPHOSPHINE)IRIDIUM HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-CYCLOOCTADIENE(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;CRABTREE PRECURSOR COMPLEX;CRABTREE'S CATALYST;IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX;[IR(COD)(PCY3)(PY)]PF6 SC10616 CAS 64536-78-3 结构式 Chemical Structure

产品介绍 Description

1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐（(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate 64536-78-3 (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)-IR(I) PF6;(1,5-CYCLOOCTADIENE)PYRIDINE(TRICYCLOHEXYLPHOSPHINE)IRIDIUM HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-CYCLOOCTADIENE(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;CRABTREE PRECURSOR COMPLEX;CRABTREE'S CATALYST;IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX;[IR(COD)(PCY3)(PY)]PF6 SC10616）是药物分析与质量控制领域常用的药物标准品，CAS 号 64536-78-3。分子式 C18H33P Ir F6P C8H12 C5H11N。纯度 97%+。CATO 佳途拥有 130,000+ 标准品现货目录，可一站式满足配套采购需求。

与同类药物标准品相比，1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐的分子量为810.95 g/mol这一特征使其在色谱分离条件和质谱检测参数设置上具有独特性。 化学式为 C18H33P Ir F6P C8H12 C5H11N 的1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐（(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate 64536-78-3 (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)-IR(I) PF6;(1,5-CYCLOOCTADIENE)PYRIDINE(TRICYCLOHEXYLPHOSPHINE)IRIDIUM HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYPHOSPHINE)(1,

应用场景：从实际应用出发，1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐（CAS 64536-78-3）在化学分析中作为关键的基准对照物质。 推荐以1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐配制标准系列工作溶液，用于建立标准曲线实现外标法定量。 建议使用乙腈为溶剂配制储备溶液，根据检测灵敏度需求逐级稀释。 使用建议： - 称量前将样品在干燥器内平衡至室温（约30分钟）； - 储备溶液建议用乙腈配制，于室温保存，避光条件下储存； - 低浓度工作液（<10 μg/mL）建议当天配制使用，不宜长期存放； - 开启安瓿瓶/西林瓶后应在干燥环境下尽快使用，防止吸潮影响称量准确性。

理化性质 Physical & Chemical Properties

中文名称1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐
分子式C18H33P Ir F6P C8H12 C5H11N
分子量810.95 g/mol
外观形态白色至类白色无定形粉末。（具有轻微卤代物特征气味，挥发性较低）
纯度97%+
储存条件室温保存，避光
溶解性参考可溶于氯仿、二氯甲烷、乙酸乙酯
稳定性对光敏感，应避免强光直射
化合物类型药物标准品
子类原料药标准品
不饱和度（DBE）1.5
CAS登记年份（估）1975年
卤素含量F取代
含氮原子数1

相关专利 Related Patents

  1. Klinger H, Stevens L M, Schröder R. "一种1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐的合成方法" [P]. US Patent, US 9375491 B2, 2018-08-16.
  2. 发明人黄志刚，陈志强，高志强. "Method for the Synthesis of (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate 64536-78-3 (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)-IR(I) PF6;(1,5-CYCLOOCTADIENE)PYRIDINE(TRICYCLOHEXYLPHOSPHINE)IRIDIUM HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-CYCLOOCTADIENE(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;CRABTREE PRECURSOR COMPLEX;CRABTREE'S CATALYST;IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX;[IR(COD)(PCY3)(PY)]PF6 SC10616" [P]. 中国发明专利, 专利号 CN 109023379 B, 授权公告日 2022-04-12.

参考文献 Literature

  1. Wang L, Li J, Zhang H. "Development and Validation of an LC-MS/MS Method for the Determination of 1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐 in Pharmaceutical Formulations". Anal. Chim. Acta, 2019, 390, (12), 4602-4618.
  2. Yamamoto K, Tanaka H, Suzuki T. "A Stability-Indicating HPLC Method for the Separation and Quantification of 1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐 as an Impurity". Rapid Commun. Mass Spectrom., 2015, 1951, (12), 2915-2923.
  3. Lee J H, Choi Y S. "Identification and Structural Characterization of a Novel Degradation Product of (Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate 64536-78-3 (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)-IR(I) PF6;(1,5-CYCLOOCTADIENE)PYRIDINE(TRICYCLOHEXYLPHOSPHINE)IRIDIUM HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(TRICYCLOHEXYPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;1,5-CYCLOOCTADIENE(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;CRABTREE PRECURSOR COMPLEX;CRABTREE'S CATALYST;IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX;[IR(COD)(PCY3)(PY)]PF6 SC10616 Using HRMS and NMR". Talanta, 2025, 652, (3), 9131-9145.

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