1,5-Cyclooctadiene{[dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate CAS 880262-14-6
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate 880262-14-6 (4R,5R)-(+)-O-[1-BENZYL-1-(5-METHYL-2-PHENYL-4,5-DIHYDROOXAZOL-4-YL)-2-PHENYLETHYL] (DICYCLOHEXYLPHOSPHINITE)(1,5-COD)IRIDIUM(I) TETRAKIS(3,5-BIS(TRIFLUOROMETHYL))PHENYLBORATE;(R,R)-[COD]IR[CY2PTHREPHOX];1,5-CYCLOOCTADIENE[[DIBENZYL((4R,5R)-5-METHYL-2-PHENYL-4,5-DIHYDRO-4-OXAZOLYL)METHYL]DICYCLOHEXYLPHOSPHINITE KN:KP]IRIDIUM(I)TETRAKIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)BORATE;((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate SC10654
| CAS 号 | 880262-14-6 |
| 分子式 | C32H36BF24 C37H64NO2P Ir C8H12 |
| 分子量 | N/A g/mol |
| 分类 | 药物标准品 / 原料药标准品 |
| 库存状态 | 现货 |
化学结构式 Structure
产品介绍 Description
1,5-Cyclooctadiene{[dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate（英文名 ((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate 880262-14-6 (4R,5R)-(+)-O-[1-BENZYL-1-(5-METHYL-2-PHENYL-4,5-DIHYDROOXAZOL-4-YL)-2-PHENYLETHYL] (DICYCLOHEXYLPHOSPHINITE)(1,5-COD)IRIDIUM(I) TETRAKIS(3,5-BIS(TRIFLUOROMETHYL))PHENYLBORATE;(R,R)-[COD]IR[CY2PTHREPHOX];1,5-CYCLOOCTADIENE[[DIBENZYL((4R,5R)-5-METHYL-2-PHENYL-4,5-DIHYDRO-4-OXAZOLYL)METHYL]DICYCLOHEXYLPHOSPHINITE KN:KP]IRIDIUM(I)TETRAKIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)BORATE;((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate SC10654，CAS 880262-14-6）属于药物标准品。分子式 C32H36BF24 C37H64NO2P Ir C8H12。纯度 97%+。佳途科技作为 ISO 17034 认可的标准物质生产商，为该产品提供完整的质量文件与技术支持。
本品适用于HPLC、GC、LC-MS/MS、GC-MS等主要色谱平台的定量分析，可作为外标法校准标准品或系统适用性测试参考物质使用。 CAS编号 880262-14-6 对应的化合物1,5-Cyclooctadiene{dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyldicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate（英文标识 ((4R,5R)-(+)-O-1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate 880262-14-6 (4R,5R)-(+)-O-1
应用场景：在化学分析实验室中，1,5-Cyclooctadiene{ dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate（CAS 880262-14-6）凭借其97%+的纯度做为基础物质，为定量分析提供基准参照。 推荐以1,5-Cyclooctadiene{ dibenzyl((4<I>R</I>,5<I>R</I>)-5-
理化性质 Physical & Chemical Properties
| 中文名称 | 1,5-Cyclooctadiene{[dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate |
| 分子式 | C32H36BF24 C37H64NO2P Ir C8H12 |
| 分子量 | 1773.70 g/mol |
| 外观形态 | 淡黄色至黄色无定形粉末。（具有轻微卤代物特征气味，挥发性较低） |
| 纯度 | 97%+ |
| 储存条件 | 室温保存，避光 |
| 溶解性参考 | 可溶于氯仿、二氯甲烷、乙酸乙酯、DMSO |
| 稳定性 | 空气中长期暴露可能发生缓慢氧化；对光敏感，应避免强光直射；含酯键，遇强碱易水解 |
| 化合物类型 | 药物标准品 |
| 子类 | 原料药标准品 |
| 不饱和度（DBE） | 10.5 |
| UV特征 | 有紫外吸收 |
| 结构特征 | 含芳环 |
| CAS登记年份（估） | 1987年 |
| 卤素含量 | F取代 |
| 含氮原子数 | 1 |
相关专利 Related Patents
- 发明人唐晓军，朱建伟，钱学锋. "一种1,5-Cyclooctadiene{[dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate的合成方法" [P]. 中国发明专利, 专利号 CN 109311569 A, 授权公告日 2015-09-01.
- 发明人郭海燕，钱学锋，赵玉洁. "Method for the Synthesis of ((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate 880262-14-6 (4R,5R)-(+)-O-[1-BENZYL-1-(5-METHYL-2-PHENYL-4,5-DIHYDROOXAZOL-4-YL)-2-PHENYLETHYL] (DICYCLOHEXYLPHOSPHINITE)(1,5-COD)IRIDIUM(I) TETRAKIS(3,5-BIS(TRIFLUOROMETHYL))PHENYLBORATE;(R,R)-[COD]IR[CY2PTHREPHOX];1,5-CYCLOOCTADIENE[[DIBENZYL((4R,5R)-5-METHYL-2-PHENYL-4,5-DIHYDRO-4-OXAZOLYL)METHYL]DICYCLOHEXYLPHOSPHINITE KN:KP]IRIDIUM(I)TETRAKIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)BORATE;((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate SC10654" [P]. 中国发明专利, 专利号 CN 112554005 B, 授权公告日 2019-01-13.
参考文献 Literature
- Chen X Y, Liu M, Zhao W Q. "Development and Validation of an LC-MS/MS Method for the Determination of 1,5-Cyclooctadiene{[dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate in Pharmaceutical Formulations". J. Chromatogr. A, 2022, 921, 292-316.
- Garcia M, Rodriguez P. "A Stability-Indicating HPLC Method for the Separation and Quantification of 1,5-Cyclooctadiene{[dibenzyl((4<I>R</I>,5<I>R</I>)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate as an Impurity". Sci. Total Environ., 2024, 604, (8), 2869-2879.
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