双(1,5-环辛二烯)三氟甲磺酸铑(I) CAS 99326-34-8

99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i) trifluoromethane sulphonate 99% bis(1,5-cyclooctadiene)rhodium(i) trifluoromethanesulfonate,97% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate,99% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulphonate99% bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate

纯度 97%+现货药物标准品
CAS 号99326-34-8
分子式CF3O3S 2*C8H12 Rh
分子量N/A g/mol
分类药物标准品 / 原料药标准品
库存状态现货

化学结构式 Structure

双(1,5-环辛二烯)三氟甲磺酸铑(I) 99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i) trifluoromethane sulphonate 99% bis(1,5-cyclooctadiene)rhodium(i) trifluoromethanesulfonate,97% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate,99% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulphonate99% bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate CAS 99326-34-8 结构式 Chemical Structure

产品介绍 Description

CATO 佳途供应的双(1,5-环辛二烯)三氟甲磺酸铑(I)（99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i) trifluoromethane sulphonate 99% bis(1,5-cyclooctadiene)rhodium(i) trifluoromethanesulfonate,97% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate,99% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulphonate99% bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate）为药物标准品，CAS 登记号 99326-34-8，分子式 CF3O3S 2*C8H12 Rh。纯度 97%+。产品现货库存充足，可提供定制化规格与批次追踪服务。

依据分子式为 CF3O3S 2C8H12 Rh 的双(1,5-环辛二烯)三氟甲磺酸铑(I)结构特征，其分子内含含砜基，羧酸类，含羟基，含醚键，含氟取代，这意味着该化合物在红外光谱中会呈现特征性的官能团伸缩振动信号。分子量 360.16 g/mol 这一参数对质谱检测中的分子离子峰识别具有直接参考价值。因分子内存在卤素取代基（F/Cl/Br/I），该化合物在质谱分析中呈现特征性的同位素分布模式，可作为定性确认的重要依据。 双(1,5-环辛二烯)三氟甲磺酸铑(I)（99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadi

应用场景：双(1,5-环辛二烯)三氟甲磺酸铑(I)（99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i)

理化性质 Physical & Chemical Properties

中文名称双(1,5-环辛二烯)三氟甲磺酸铑(I)
分子式CF3O3S 2*C8H12 Rh
分子量360.16 g/mol
外观形态白色至类白色结晶性粉末。（具有轻微卤代物特征气味，含硫化合物特征性气味，挥发性较低）
纯度97%+
储存条件阴凉处（≤25°C）保存，密封防潮
溶解性参考可溶于甲醇、乙醇、DMSO
稳定性具有吸湿性，开封后应立即密封；含酯键，遇强碱易水解
化合物类型药物标准品
子类原料药标准品
不饱和度（DBE）2.5
CAS登记年份（估）1985年
卤素含量F取代
含硫原子数1

相关专利 Related Patents

  1. Yamamoto T, Johnson M A, Chen K W. "一种双(1,5-环辛二烯)三氟甲磺酸铑(I)的合成方法" [P]. US Patent, US 11749941 B2, 2017-06-23.
  2. 发明人赵玉洁，张德明，李文辉. "Method for the Synthesis of 99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i) trifluoromethane sulphonate 99% bis(1,5-cyclooctadiene)rhodium(i) trifluoromethanesulfonate,97% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate,99% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulphonate99% bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate" [P]. 中国发明专利, 专利号 CN 109941073 B, 授权公告日 2024-01-12.
  3. 发明人刘建华，马晓峰，冯建国. "A Process for Preparing High-Purity 99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i) trifluoromethane sulphonate 99% bis(1,5-cyclooctadiene)rhodium(i) trifluoromethanesulfonate,97% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate,99% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulphonate99% bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate" [P]. 中国发明专利, 专利号 CN 111556298 B, 授权公告日 2019-02-18.

参考文献 Literature

  1. Martinez C, Lopez D R. "Development and Validation of an LC-MS/MS Method for the Determination of 双(1,5-环辛二烯)三氟甲磺酸铑(I) in Pharmaceutical Formulations". Sci. Total Environ., 2016, 2226, 7975-7980.
  2. Smith J A, Johnson M B. "A Stability-Indicating HPLC Method for the Separation and Quantification of 双(1,5-环辛二烯)三氟甲磺酸铑(I) as an Impurity". Phytochemistry, 2023, 1635, (8), 613-643.
  3. Zhou X P, Huang L, Wu G. "Identification and Structural Characterization of a Novel Degradation Product of 99326-34-8 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Boc-D-His(3-Bom)-OH N-tert-Butyloxycarbonyl-N'-benzyloxymethyl-L-histidine bis(1,5-cyclooctadiene)-trifluoromethanesulfitorhodium (i) bis(1,5-cyclooctadiene)rhodium(i) trifl& bis(1,5-cyclooctadiene)rhodium(i) trifluoromethane sulphonate 99% bis(1,5-cyclooctadiene)rhodium(i) trifluoromethanesulfonate,97% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulfonate,99% bis(1,5-cyclooctadiene)rhodium(i)trifluoromethanesulphonate99% bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate Using HRMS and NMR". Environ. Sci. Technol., 2024, 777, (3), 2962-2983.
  4. Kim S H, Park J Y. "Forced Degradation Studies to Evaluate 双(1,5-环辛二烯)三氟甲磺酸铑(I) Profile in Drug Substances According to ICH Guidelines". Anal. Chim. Acta, 2017, 2227, (7), 872-875.

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