Grubbs 催化剂<SUP>®</SUP> M101 CAS 250220-36-1

Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN ADDUCT;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(IV) DICHLORIDE;DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II);NEOLYST(TM) M1;UMICORE M1 SC10228

纯度 97%+现货药物标准品
CAS 号250220-36-1
分子式C51H90Cl2P2Ru
分子量937.18 g/mol
分类药物标准品 / 原料药标准品
库存状态现货

化学结构式 Structure

Grubbs 催化剂<SUP>®</SUP> M101 Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN ADDUCT;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(IV) DICHLORIDE;DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II);NEOLYST(TM) M1;UMICORE M1 SC10228 CAS 250220-36-1 结构式 Chemical Structure

产品介绍 Description

CAS 250220-36-1 对应的Grubbs 催化剂<SUP>®</SUP> M101（Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN ADDUCT;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(IV) DICHLORIDE;DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II);NEOLYST(TM) M1;UMICORE M1 SC10228）为 CATO 佳途药物标准品产品线成员。分子式 C51H90Cl2P2Ru，分子量 937.18。纯度 97%+。所有批次均经 HPLC/NMR 等多项检测确认，质量稳定可溯源。

与同类药物标准品相比，Grubbs 催化剂<SUP>®</SUP> M101的分子量为937.18 g/mol这一特征使其在色谱分离条件和质谱检测参数设置上具有独特性。 Grubbs 催化剂<SUP>®</SUP> M101（Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN ADDUCT;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;BIS(TRICYCLOHEXYLPHOSPHINE)-3

应用场景：Grubbs 催化剂<SUP>®</SUP> M101（Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN AD

理化性质 Physical & Chemical Properties

中文名称Grubbs 催化剂<SUP>®</SUP> M101
分子式C51H90Cl2P2Ru
分子量937.18 g/mol
外观形态类白色至淡黄色无定形粉末。（具有轻微卤代物特征气味，挥发性较低）
纯度97%+
储存条件室温保存，避光
溶解性参考可溶于氯仿、二氯甲烷、乙酸乙酯
稳定性空气中长期暴露可能发生缓慢氧化；对光敏感，应避免强光直射
化合物类型药物标准品
子类原料药标准品
不饱和度（DBE）6.0
UV特征有紫外吸收
结构特征含芳环
CAS登记年份（估）2025年
卤素含量Cl取代

相关专利 Related Patents

  1. 发明人王建平，孙丽萍，朱建伟. "一种Grubbs 催化剂<SUP>®</SUP> M101的合成方法" [P]. 中国发明专利, 专利号 CN 111330766 B, 授权公告日 2022-03-18.
  2. Sørensen M, Martínez F, Johansson L. "Method for the Synthesis of Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN ADDUCT;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(IV) DICHLORIDE;DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II);NEOLYST(TM) M1;UMICORE M1 SC10228" [P]. European Patent, EP 3290183 A1, 2022-07-06.

参考文献 Literature

  1. Lee J H, Choi Y S. "Development and Validation of an LC-MS/MS Method for the Determination of Grubbs 催化剂<SUP>®</SUP> M101 in Pharmaceutical Formulations". Food Chem., 2020, 1781, (4), 4436-4464.
  2. Mueller T, Schmidt R K. "A Stability-Indicating HPLC Method for the Separation and Quantification of Grubbs 催化剂<SUP>®</SUP> M101 as an Impurity". Chemosphere, 2015, 1711, 5003-5033.
  3. Yang F, Sun W, Liu J. "Identification and Structural Characterization of a Novel Degradation Product of Bis(tricyclohexylphosphine)-3-phenyl-1H-inden-1-ylideneruthenium(II) dichloride 250220-36-1 (3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE;(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(IV) DICHLORIDE TETRAHYDROFURAN ADDUCT;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(II) DICHLORIDE;BIS(TRICYCLOHEXYLPHOSPHINE)-3-PHENYL-1H-INDEN-1-YLIDENERUTHENIUM(IV) DICHLORIDE;DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II);NEOLYST(TM) M1;UMICORE M1 SC10228 Using HRMS and NMR". Phytochemistry, 2019, 1972, 5568-5578.

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